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Limin Jin Xiaoli Yang Siufung Yu Puran Zheng Xian Chen Shumin Xiao Qinghai Song 《Journal of the American Ceramic Society》2022,105(9):5764-5773
Ultraviolet (UV) lasers with dynamic wavelength-tunability and high monochromaticity are crucial in a multitude of practical applications yet still remarkable challenges. Here, we show wide wavelength-tuning of single-mode UV lasing based on lanthanide-doped upconversion nanoparticles (UCNPs). The rationally designed Yb3+/Er3+/Tm3+/Gd3+/Ce3+ co-doped multilayer UCNPs, which exhibits a broad gain spectrum with the full width of half maximum of around 57 nm in the UV regime, are developed. More importantly, by taking advantages of a diffraction grating as the tuning component, stable single-mode emission can be achieved in the UCNPs-based external-cavity-extended Fabry–Pérot laser at room temperature. Specifically, the lasing threshold is around 137 µJ cm–2, which is two orders of magnitude lower than that in the previously reported articles. Precise wavelength-tuning from 310 to 363 nm can be realized by adjusting the Littrow angle. This achievement highlights a portable alternative to continuously wideband-tunable UV lasers and opens up new opportunities for constructing compact solid-state UV photon sources. 相似文献
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硅质、铝质、镁质和铬质耐火材料中MgO、Na2O、Fe2O3、MnO、Cr2O3、TiO2、P2O5、SiO2、CaO、K2O、Al2O3等组分含量的分析,一般采用EDTA滴定法、分光光度法、原子吸收光谱法测定,操作繁琐,耗时长;而使用X射线荧光光谱法分析时,4种基体的耐火材料需要采用不同的熔融方法和校准曲线。为了将4种基体的耐火材料统一制样方法,并使用同一组校准曲线同时测定MgO、ZrO2、Na2O、ZnO、NiO、Fe2O3、MnO、Cr2O3、V2O5、TiO2、P2O5、SiO2、CaO、K2O、Al2O3等主次组分,实验选用3套国外耐火材料标准样品,并对熔融温度、时间、稀释比等熔融制样条件进行优化;通过峰位及强度扫描确定各元素电压、电流、准直器等条件,达到灵敏度与分辨率最佳,通过扫描PHA确定脉冲宽度,提高准确度。理论α系数校正元素间吸收增强效应,用比例法计算校正谱线重叠,优化校准曲线,提高分析方法准确度。各组分校准曲线线性相关系数R2在0.9940~0.9999之间。按照实验方法熔融JRRM507、JRRM803、JRRM129 3个标准样品,进行方法精密度和熔片精密度试验,结果表明重复性均能达到GB/T 21114—2007要求。按照实验方法选择镁铬矿、高岭土、铝土矿3类标准物质进行正确度验证,VS P14/3、UNS KK、ZBK394标准物质中MgO、ZrO2、Na2O、ZnO、NiO、Fe2O3、MnO、Cr2O3、V2O5、TiO2、P2O5、SiO2、CaO、K2O、Al2O3等主次组分的测定结果与认定值相吻合。 相似文献
4.
低成本、小型化的波长扫描半导体激光器在光纤传感系统中有着重要作用。设计了一种可进行温度调谐的半导体激光光源驱动电路。该电路系统以ARM单片机作为控制中心,利用热敏电阻采样激光工作温度,并通过半导体制冷器(TEC)进行温度调节,使得激光器能够根据温度调谐实现波长扫描;同时通过背向光探测器(PD)采样激光输出功率,并通过改变半导体激光驱动电流实现对激光输出功率的控制,使得激光器在温度变化时输出光功率保持稳定。实验结果表明,该电路能够长时间可靠地工作,激光器能够实现的最大波长调谐范围为5nm,且输出光功率在整个波长扫描过程中保持稳定。 相似文献
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设计了一种基于可调谐半导体激光吸收光谱技术的甲烷(CH4)气体监测装置,该装置具有温度监测范围大、监测精度高和实时监测的优点。监测装置的激光光源为波长1650 nm的反馈式激光器,应用波长调谐与锁相放大器技术,对周围环境进行温度补偿与背景扣除,可以较准确地测量周围环境中CH4的体积分数。实验表明,当CH4体积分数小于1%时,该装置的监测精度为±0.02%;当CH4体积分数大于1%时,装置监测误差小于±0.8%,实时监测的最长响应时间为10 s。装置的温度范围为0~40℃,可满足大多数工业生产中对CH4等气体体积分数的监测需求。 相似文献
7.
Modular Self‐Assembling Peptide Platform with a Tunable Thermoresponsiveness via a Single Amino Acid Substitution 下载免费PDF全文
《Advanced functional materials》2018,28(35)
The introduction of a stimulus‐responsive property is an effective way to increase the applicability of functional materials in the field of nanobiotechnology. Herein, a peptide platform is devised for constructing elastin‐like peptide amphiphiles (ELPAs) that exhibit a temperature‐responsiveness that can be easily tuned via a single N‐terminal amino acid substitution at the final step of peptide synthesis. Due to the modular property of peptides, the platform based on a miniaturized elastin‐like peptide (MELP) can be conjugated with various bioactive peptide sequences in diverse macromolecular topologies. First, the MELP platform is coupled with a short linear RGD peptide. The ELPAs of the peptide conjugates exhibit rapid aggregation (coacervation) and retard disaggregation in response to heating and cooling, respectively. Second, the platform is grafted with an α‐helical guest peptide in a lariat‐type structure, which forms ELPAs that undergo faster disassembly than the ELPAs without the guest peptide in response to temperature increases. Interestingly, the critical temperatures for the thermoresponsive behaviors are commonly dependent on the hydrophobic and aromatic properties of the N‐terminal amino acid residues. These results suggest that this peptide platform possesses great potential for use in the development of smart materials in wide‐ranging applications related to temperature change. 相似文献
8.
H. Ahmad N. F. Azmy S. A. Reduan N. Yusoff L. Bayang M. Z. Zulkifli 《Journal of Modern Optics》2020,67(11):1022-1030
A tunable, passively Q-switched thulium doped fluoride fibre (TDFF) laser using a reduced-graphene oxide-silver (rGO-Ag) thin film as a saturable absorber (SA) for S band operation is proposed and its efficacy demonstrated. Over a pump power range of 91.4?mW up to 158.6?mW, passively generated Q-switched pulses are observed with repetition rates from 20 to 34.5?kHz and pulse widths from 3.1 to 7.1?µs. The highest pulse energy observed is 101.2?nJ with a signal to noise ratio of ~42?dB. The proposed laser has a tuning range ~52?nm from 1458 to 1510?nm with a tunable bandpass filter (TBPF) introduced into the cavity. 相似文献
9.
Chenxi Wang Zujian Wang Xiaoming Yang Chao He Xifa Long 《Journal of the American Ceramic Society》2020,103(11):6445-6452
Tunable dielectric materials have drawn much attention due to their wide applications including capacitors and microwave tunable devices. Ferroelectrics materials have special spontaneous polarization which can be reversibly switched by an external electric field. Therefore, tunable dielectric constant can be easily achieved in ferroelectrics. However, the study of nonlinear dielectric response induced by defect dipoles is rarely concerned. Here, we report the effects of defect dipoles on tunable dielectric response under alternative current (AC) and direct current (DC) electric field in defect dipoles introduced Pb(Lu1/2Nb1/2)O3–PbTiO3 ceramics. A modified Rayleigh model is proposed to successfully characterize dielectric nonlinearity and reveals the interaction between domain walls and defect dipoles. The defect dipoles had more sensitive effect on dielectric response under AC field than that of defect dipoles-free samples. The drop of intrinsic dielectric contribution under AC field results from the detriment effect of defect dipoles. The irreversible contribution is altered by the movements of defect dipoles under AC field, subsequently inducing the nonlinearity of dielectric response. Samples with defect dipoles have larger tunable scope of dielectric properties than that of defect dipoles-free samples. The present work discovers the potential of application of defect dipoles-tuned dielectric response ferroelectrics in devices which requires both high AC and DC biases, and help to better understand the complex dielectric response of ferroelectrics. 相似文献
10.
Chao Xia Mengmeng Cao Jinfeng Xia Danyu Jiang Guohong Zhou Caiyan Yu Huili Li 《Journal of the American Ceramic Society》2020,103(8):4507-4516
In this work, we synthesized a series of novel carbon dots (CDs) by using phenylenediamines (three isomers: o-phenylenediamine, m-phenylenediamine, and p-phenylenediamine) as starting materials via facile solvothermal approach. As-prepared CDs could emit bright blue, green, yellow, orange, and red light with relatively high PLQY, individually. Optical properties could be controlled by simply varying reaction parameters. The luminescent mechanism was investigated and analyzed in detail. Finally, the blue-emitting CDs and green-emitting CDs showed many appealing properties, such as high sensitivity (limit of detection = 4.52 and 3.50 nmol/L), quick response (<2 minutes), broad response window (0-70 nmol/L), and excellent selectivity for detecting Cr6+ and Al3+ cations, respectively. Thus, they have potential to be developed as the corresponding optical probes. While as-prepared orange-emitting CDs could be applied as a bio-imaging reagent due to its long-wavelength emission, relatively high PLQY, low toxicity, excellent water solubility, and good biocompatibility. 相似文献